سال انتشار: ۱۳۸۶

محل انتشار: پانزدهمین همایش انجمن بلورشناسی و کانی شناسی ایران

تعداد صفحات: ۵

نویسنده(ها):

Ali. R Rezvani – Department of Chemistry, University of Sistan and Baluchestan,P. O. Box 98135-674, Zahedan, Iran
Hassan Hadadzadeh – Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111, Iran
Hamideh Saravania – Department of Chemistry, University of Sistan and Baluchestan,P. O. Box 98135-674, Zahedan, Iran
Ghobad Mansouri – Department of Chemistry, University of Sistan and Baluchestan,P. O. Box 98135-674, Zahedan, Iran

چکیده:

New five-coordinated CuII complexe, [Cu(terpy)(phen-dione)](PF6)2, (terpy= 2,2′;6′,2 – terpyridine and phen-dione=1,10-phenanthroline-5,6-dione) has been prepared.The complex of [Cu(terpy)(phen-dione)](PF6)2 crystallized with one molecule of acetonitrile with empirical formula C29 H20 Cu F12 N6 O2 P2, in a monoclinic crystalsystem and space group of P21/c with a= 8.440(2)Å, b= 26.067(5)Å, c= 15.015(3)Å, β= ۹۲٫۸۵۵(۱۸)º, V=3299.1(12)Å۳ and Z=4.ORTEP drawing of [Cu(terpy)(phendione)]( PF6)2.CH3CN shows that the coordination geometry around CuII is a distorted square- pyramidal. Due to steric hidereance of PF6 – in unit cell, the terpy ligands in each complex cations can not interact via the two π- electronic systems.