سال انتشار: ۱۳۸۳

محل انتشار: نهمین کنگره ملی مهندسی شیمی ایران

تعداد صفحات: ۹

نویسنده(ها):

Pakdehi – Chemical Engineering Department,Faculty of Engineering, University of Tehran, Tehran, Iran ، Faculty of Material and Chemical Engineering, Malek Ashtar University of Technology, Tehran, Iran
Moghaddam – Faculty of Material and Chemical Engineering, Malek Ashtar University of Technology, Tehran, Iran
Abolhamd – Chemical Engineering Department, Faculty of Engineering, University of Tehran, Tehran, Iran
Sohrabi – Chemical Engineering Faculty, Amir Kabir University of Technology, Tehran, Iran

چکیده:

A new modified process for preparation of acetylhydrazine (AH) in the semibatch reactor has been described. The synthesis of AH is based on the reaction of hydrazine with ethyl acetate in alcoholic solvents. The effect of lower alcoholic solvent type, molar ratio of methanol to ethyl acetate, molar ratio of ethyl acetate to hydrazine, stirrer speed and the reaction temperature on the molar yield of AH were studied and an
optimum condition was obtained .The average molar yield of AH was about 97.5% under the optimum operational conditions.