سال انتشار: ۱۳۸۶

محل انتشار: پانزدهمین همایش انجمن بلورشناسی و کانی شناسی ایران

تعداد صفحات: ۴

نویسنده(ها):

Mohammad Yazdanbakhsh – Department of Chemistry,faculty of Science,Ferdowsi University of Mashhad,Iran
Nahid Lotfian – Department of Chemistry,faculty of Science,Ferdowsi University of Mashhad,Iran

چکیده:

A series of novel oxo-centered trinuclear crystals,[M(2)M′O(C(3)H(3)O(2))6(H(2)O) (L)(2)](+)(M=Cr, M′= Cr,Fe;L=H(2)O,CH(3)OH) have been synthesized. The complexes werecharatrized by elemental analyses, Infrared and electronic spectroscopy and DSC analyses..These complexes containing unsaturated carboxylate bridging ligand thatcauses them to have potential scops for polymerization in the solid state by crosslinking of substituents. The trinuclear structure of complexes remains when the water molecules are replaced by methanol.